ratio of n-butyraldehyde and isobutyraldehyde is 3. The reaction processes at 0.7-3MPa and 80-120°C, when rhodium is used as the catalyst. The products ratio of n-butyraldehyde and isobutyraldehyde of 8-16 can be achieved. The catalysts of nickel or copper in gaseous phase or nickel in liquid phase are used for hydrogenation. Second process is aldol condensation, in this reaction; two molecules of acetic aldehyde condense by dehydration. The product crotonaldehyde is then transformed into n-butanol