biomass, and have immense utilization in transportation and diverse industrial mechanisms. Secondary biofuels can be produced in the form of solids (e.g. charcoal, fuelwood, wood pellets), or liquids (e.g. ethanol, biodiesel, butanol, pyrolysis oils and bio-oil), or gases (e.g. biogas, synthesis gas, methane and hydrogen) (Nigam & Singh, 2011). The secondary biofuels can be segregated into first, second and third-generation biofuels based on the substrate availability, technology maturity and GHG gas emission